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Question

One mole of ideal gas is allowed to expand reversibly and adiabatically from a temperature of 27oC. If the work done by the gas in the process is 3 kJ, the final temperature will be equal to (Cv=20 J/K mol):

A
100 K
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B
450 K
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C
150 K
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D
400 K
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Solution

The correct option is C 150 K
Solution:- (C) 150K
From first law of thermodynamics,
ΔU=q+W
As we know that, for adiabatic condition,
q=0
ΔU=W.....(1)

At constant volume,
ΔU=nCvΔT.....(2)
From eqn(1)&(2), we have
W=nCvΔT.....(3)

Given:-
Ti=27=(27+273)K=300K
Tf=T(say)=?
ΔT=TfTi=(T300)
Cv=20J/Kmol
W=3kJ=3×103J[Work done by the gas is negative]

Substituting all these values in eqn(3), we have
3000=1×20×(T300)
T300=150
T=300150=150K
Hence the final temperature is 150K.

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