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Question

One mole of NH4Cl(s) is kept in an open container & then covered with a lid. The container is now heated up to 600K where NH4Cl(s) completely dissociates into NH3(g) & HCl(g). If a volume of the container is 24.63 liters, calculate what will be the final pressure of the gases inside the container? Assume that outside air is at 300K and 1 atm pressure.

A
0.5 atm;
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B
2.5 atm;
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C
1.5 atm;
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D
None of these
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Solution

The correct option is D None of these
NH4Cl(s)1 molNH3(g)1 mol+HCl(g)1 mol

P=nRTV=2×0.0821×60024.63=4atm

Thus, the total pressure of gases inside container is 4 atm.

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