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Question

One mole of NH4Cl(s) is kept in an open container & then covered with a lid. The container is now heated to 600K where all NH4Cl(s) dissociates into NH3 and HCl(g). If volume of the container is 24.63 litres, calculate what will be the final pressure of gases inside the container. Also find whether the lid would stay or bounce off if it can with stand a pressure difference of 5.5 atm. Assume that outside air is at 300K and 1 atm pressure.

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Solution

Given that NH4Cl1moleNH31mole+Cl1mole
PV=nRT
=2×82.11000×60024.63
=821×325×24.63=4
Pressure= 41=3 atm
So, the lid does not bounce.

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