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Question

One mole of non-ideal gas undergoes a change of state (1.0 atm, 3.0 L, 200 K) to (4.0 atm, 5.0 L, 250 K) with a change in internal energy ΔU = 40 L-atm. The change in enthalpy of the process in L-atm is :

A
43
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B
57
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C
42
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D
None of these
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Solution

The correct option is B 57
When both P and V are changing,
ΔH=ΔU+Δ(PV)=ΔU+(P2V2P1V1)=40+(203)=57 L atm

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