One gram of ice is mixed with one gram of steam. After thermal equilibrium is reached, the temperature of the mixture is (Latent heat of fusion of ice; Lice=80cal/g, latent heat of condensation of vapour; LV=540cal/g)
A
100∘C
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B
55∘C
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C
50∘C
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D
0∘C
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Solution
The correct option is A100∘C We know, Latent heat of fusion of ice; Lice=80cal/g Latent heat of condensation; LV=540cal/g of vapour. Specific heat capacity of water; c=1cal/g∘C Heat supplied by steam if it is to condense totally and convert into water at 100∘C. Q1=1×LV=540cal Heat required by ice to convert totally into water at 0∘C Q1=1×Lice=1×80=80cal Heat required by ice to convert totally into water at 100∘C Q3=1×Lice+1×C×ΔT=1×80+1×1×(100−0)=80+100=180cal Since Q1>Q3, entire steam will not condense and the final temperature of mixture of water and steam will be 100∘C.