Only two isomeric monochloro derivatives are possible for (excluding stereo ) :

n - butane

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2, 2 - dimethylpentane

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benzene

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neopentane

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Solution

The correct option is A n - butane
n - butane can have two isomeric monochloro derivatives (at position 1 and 2).
Benzene and neopentane will have one only.
And 2, 2 - dimethylpentane will have 3.

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