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Polysaccharides

Order of bond...

Question

Order of bond angle in PF3 PCl3 PI3 PBr3

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Q. Assertion :Bond angle of

{P F}_{3} > P {C l}_{3}

but bond angle of

P {C l}_{3} < P {B r}_{3}

Reason: The bond angles show an increase on decreasing electronegativity of attached other atom on central atom but in

{P F}_{3}

p π - d π

bonding results in an increase in bond angle.

Q. Which of the following is incorrect order of

X - P - X

Q. Which statement is correct for the conversion of ROH to RX by reagents

(S O C l_{2}, P B r_{3}, P C l_{3}, P I_{3})

and TsCl compared to using HX?

Q. Which statement is correct for the conversion of

R O H

R X

A (S O C l_{2}, P B r_{3}, P C l_{3}

P I_{3})

compared to using

H X

?

Q. The decreasing order of bond angles in

B F_{3}, N H_{3}, P F_{3}

I_{3}^{-}

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