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Question

Order of paramagnetic character among following elements is/are:

A
Mn>Fe>Cr
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B
Fe>Zn>Cr
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C
Cr>Fe>Zn
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D
Cr>Mn>Fe
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Solution

The correct options are
B Cr>Fe>Zn
D Cr>Mn>Fe
Cr[Ar] 4s1 3d5
Fe[Ar] 4s2 3d6
Zn[Ar] 4s2 3d10
Mn[Ar] 4s2 3d5

The number of unpaired electrons present in Cr, Fe, Zn and Mn are 6, 4, 0 and 5 respectively.
Greater is the number of unpaired electrons, greater is the paramagnetic character.
Order of paramagnetic character among following elements are Cr>Fe>Zn and Cr>Mn>Fe

Hence, the correct options are C and D.

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