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Question

Orthoboric acid contains :

A
Pyramidal BO33 units
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B
.Linear BO33 units
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C
T-shaped BO33 units
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D
Triangular BO33 units
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Solution

The correct option is D Triangular BO33 units
The simplest borate anion, the orthoborate ion, BO33 is known. In this it adopts a near trigonal planar structure. It is a structural analogue of the carbonate anion CO32, with which it is isoelectronic. Simple bonding theories point to the trigonal planar structure. In terms of valence bond theory the bonds are formed by using sp2 hybrid orbitals on boron as shown in figure.
129874_24676_ans.png

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