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Reactions of Aryl Amines (Diazo Salts)

Out of chloro...

Question

Out of chlorobenzene and benzyl chloride, which one gets easily hydrolysed by aqueous NaOH and why?

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Solution

Benzyl chloride is easily hydrolysed by aqueous NaOH due to the formation of resonance stabilised carbocation.

Benzyl carbocation is highly stable due to resonance.

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Reactions of Aryl Amines (Diazo Salts)

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