Calculating velocity of particles using de-Broglie's relation
According to de-Broglie’s relation:
λ=hmv
where, λ is wavelength, ℎ is Planck’s constant 𝑚 is mass and 𝑣 is velocity.
→ λ α1mv
From this, we observed that wavelength is inversely proportional to mass and velocity.
For the same wavelength, object with large mass, will have smaller velocity and object with smaller mass will have larger velocity, in order to keep the value of wavelength constant.
Among proton and electron, the mass of electron is less than the mass of proton.
Mass of electron(me)=9.1×10−31kg
Mass of proton(mp)=1.6726×10−27kg
Therefore, electron will have higher velocity as compared to the velocity of proton.