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B
best oxidising agent is FeO2−4
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C
best oxidising agent is FeCl3
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D
best reducing agent is FeO2−4
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Solution
The correct options are A best reducing agent is Fe B best oxidising agent is FeO2−4 Species which has least oxidation number is oxidised and thus is the best reducing agent while species which has maximum oxidation number is reduced and thus is the best oxidising agent.
The oxidation number of Fe in Fe,FeCl2,FeCl3 and FeO2−4 is 0,+2,+3 and +6 respectively.
The oxidation number of iron in iron metal is lowest. It is easily oxidized. Hence, it is best reducing agent. Thus, option (A) is correct.
The oxidation number of FeO2−4 is highest. It is easily reduced. Hence, it is best reducing agent. Thus, option (B) is also correct.