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Question

Oxidation of HCl with oxygen releases :

A
H2
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B
Cl2
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C
O2
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D
H2S
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Solution

The correct option is B Cl2
Before electrolytic methods were used for chlorine production, the direct oxidation of hydrogen chloride with oxygen or air was exercised in the Deacon process 4HCl+O22Cl2+2H2O
This reaction is accomplished with the use of copper(II) chloride (CuCl2) as a catalyst and is performed at high temperature (about 400oC). The amount of extracted chlorine is approximately 80%. Due to the extremely corrosive reaction mixture, industrial use of this method is difficult and several pilot trials failed in the past.

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