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Question

Oxygen and hydrogen gas are produced at the anode and cathode respectively, during the electrolysis of fairly concentrated aqueous solution of:

A
K2SO4
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B
AgNO3
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C
H2SO4
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D
NaOH
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Solution

The correct options are
B H2SO4
C K2SO4
D NaOH
As the reduction potential of K+ and Na+ are lower than hydrogen ion, hydrogen ion gets preferably reduced and hydrogen gas is produced at the cathode.
Also, as oxidation potential of OH is higher than sulphate ion, it will oxidise first and oxygen is evolved at the anode.
Hence, a fairly concentrated electrolytic aqueous solution of K2SO4, H2SO4 and NaOH produces oxygen and hydrogen gas.

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