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Question

Oxygen is more electronegative than sulphur, yet H2S is acidic while H2O in neutral. This is because

A
water is a highly associated compound
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B
HS bond is weaker than HO bond
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C
H2S is a gas while H2O is a liqiud
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D
the molecular weight of H2S is more than that of H2O
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Solution

The correct option is B HS bond is weaker than HO bond
Electronegativity of oxygen is more than sulphur and so, HO bond is stronger than HS bond. HS bond easily donates proton.
Hence, H2S is more acidic than H2O.

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