Ozonolysis of 2-5 gives total number of carbonyl compounds -

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Standard XII

Chemistry

Heterolytic Cleavage

Ozonolysis of...

Question

Ozonolysis of $2, 5 -dimethyl-2,4-hex-diene$ gives total number of carbonyl compounds :

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Solution

Total number of carbonyl compounds obtained by ozonolysis of 2,5-dimethyl-2,4-hex-diene is 3.

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The structure of the carbonyl compound P, which gives positive iodoform test undergoes reaction with MeMgBr followed by dehydration to give an olefin Q. Ozonolysis of Q leads to a dicarbonyl compound R, which undergoes intramolecular aldol reaction to give predominantly S.

The structure of the carbonyl compound P is:

Q. A carbonyl compound P, which gives positive iodoform test, undergoes reaction with MeMgBr followed by dehydration to give an olefin Q. Ozonolysis of Q leads to a dicarbonyl compound R, which undergoes intra-molecular aldol reaction to give predominantly S.

The structure of the carbonyl compound P, is

Q. The number of different types of structures of carbonyl compounds which can be obtained by reductive ozonolysis of the above given figure is :

Q. A carbonyl compound P, which gives positive iodoform test, undergoes reaction with MeMgBr followed by dehydration to given an olefin Q. Ozonolysis of Q leads to a dicarbonyl compound R, which undergoes intramolecular-aldol reaction to give predominantly S.

P = 1. M e M g B r - --------------- \to 2. H^{+}, H_{2} O 3. H_{2} S O_{4} / h e a t Q 2. O_{3} / Z n - H_{2} O - -------- \to R O H^{-} - -- \to h e a t S

The structure of the carbonyl compound P, is

Q. A carbonyl compound P (from i-iii), which gives positive iodoform test, undergoes with MeMgBr followed by dehydration to give an olefin Q. Ozonolysis of Q leads to a dicarbonyl compound R, which undergoes intramolecular aldol reaction to give predominantly S.

2. Product S is :

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Ozonolysis of 2,5-dimethyl-2,4-hex-diene gives total number of carbonyl compounds :

Total number of carbonyl compounds obtained by ozonolysis of 2,5-dimethyl-2,4-hex-diene is 3.

Ozonolysis of $2, 5 -dimethyl-2,4-hex-diene$ gives total number of carbonyl compounds :