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Question

a first order reaction is 75% complete in 60 min. find the half life of initial reactants that will react in 10 hr

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Solution

Order of reaction =1
Let initial concentration of reactant be[A]o =100
[A]t =100-75=25

Rate law for first order reaction :
k= (2.303/t) log [A]o/[A]t
k=2.303/60 log100/25 =0.0231

t1/2 =0.693/k =0.693/0.0231 =30 minutes.




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