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Question

An organic compound 'A' is a constituent of antifreeze. The compound on heating with oxygen forms another compound B which has molecular formula C2H4O2. Identify the compound 'A' and 'B'. Write the chemical equation of the reaction that takes place to form the compound 'B'.

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Solution

Compound 'A' is ethanol 'C2H5OH'
Compound 'B' is ethanoic acid 'CH
3COOH' which can be also write as C2H4O2
B cannot be aldehyde because final oxidation product is carboxylic acid but if oxidation is carried out in presence of some mild oxidising agent, then it may results aldehyde.

C2H5OH + O2 (strong oxidising agent) ------> CH3COOH + H2O

C2H5OH + O2 (weak/mild oxidising agent, PCC) ------> CH3CHO + H2O


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