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Question

an organic compound on analysis is found have the following composition. Carbon=41.4%, hydrogen=5.75%, nitrogen=16.08% and the rest is oxygen. find out the empirical formula of the compound

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Solution

Consider the total mass of compound is 100 g
Mass of element in 100 g of compound is equal to mass % of element.
Number of moles = mass / molar mass of element

Mass %
Moles of atom(% of mass/atomic mass) simplest mole ratio
Carbon 41.4% 41.4 /12 = 3.45 3.45/1.14≈ 3
Hydrogen 5.75 % 5.75/1 =5.75 5.75/1.14≈ 5
Nitrogen 16.08 % 16.08/14=1.14 1.14/1.14=1
Oxygen 36.77 % 36.77/16=2.29 2.29/1.14≈ 2

Thus empirical formula of a compound is C3H5NO2

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