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Question

Atwhat temperature is the root mean square speed of an atom in an argongas cylinder equal to the rms speed of a helium gas atom at –20 °C? (atomic mass of Ar = 39.9 u, of He = 4.0 u).

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Solution

Temperatureof the helium atom, THe= –20°C=253 K

Atomicmass of argon, MAr= 39.9 u

Atomicmass of helium, MHe= 4.0 u

Let,(vrms)Arbe the rms speed of argon.

Let(vrms)Hebe the rms speed of helium.

Therms speed of argon is given by:

…(i)

Where,

Ris the universal gas constant

TAris temperature of argon gas

Therms speed of helium is given by:

…(ii)

Itis given that:

(vrms)Ar=(vrms)He

=2523.675 = 2.52 × 103K

Therefore,the temperature of the argon atom is 2.52 × 103K.


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