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Question

calculate how muc heat must be supplied to evaporate 18g of water at 298 K

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Solution

Number of moles in 18 g H2O(l) is = 18g/18 g mol-1 = 1mol

ΔvapUovapHo − pΔV = ΔvapHo −ΔngRT

ΔvapHo – ΔngRT = 40.66 kJ mol-1 -(1)(8.314 JK-1 mol-1)(373k)(10-3KJ J-1)

ΔvapUo = 40.66 kJ mol-1 – 3.10 kJ mol-1

= 37.56kJ mol


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