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Question

GIVE REASON WHY REACTIION OF AN ALKYL HALIDE WITH Aq.koh GIVES ALCOHOL BUT WITH ALCOHOLIC KOH IT PRODUCES AN ALKENE.

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Solution

Alkyl halide with substitution reaction produces alcohol and with elimination reaction produces alkenes. Medium which facilitate these specific type of reaction will produce product accordingly.

KOH in Water gives OH- ions which are strong nucleophile and facilitate the substitution reaction while KOH in ethyl alcohol produces C2H5-O- ions which due to larger size observe hindrance when attack on alpha carbon so as a strong base it removes hydrogen from beta carbon and is responsible for elimination reaction.


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