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Question

How many moles of butane must burn to increase the temperature of 10dm3 of water from 300 C to 100o C? Given that dH(comb) of butane, density of water and specific heat of water are -2.89*103 KJ/mol, 1.0 g/cm3 .4.184JK -1 g -1 .

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Solution

Volume = 10 dm3

1 dm = 10cm

so, volume= 104cm3

mass = volume x density

= 104 x 1

= 104g

c = 4.184 JK-1g-1

ΔT = Tf-Ti

= 373-303

= 70 K

q = mcΔT

= 104 x 4.184 x 70 J

For butane ΔH = 2.89 x 106 J/mole

2.89 x 106 J is obtained by = 1 mole of butane

1 J is obtained by = 1/2.89 x 106 mole

104 x 4.184 x 70 J is obtained by= 1 x 104 x 4.184 x 70 /2.89 x 106 mole

= 101.34 x 10-2 mole


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