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Question

In an experiment 4.90g of copper oxide was obtained from 3.92g of copper . In another experiment 4.55g of copper oxide gave on reduction 3.64g of copper . Show with the help of calculations that these figures verify the law of constant propotions.

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Solution

The law of constant proportion or law of definite proportion states that in a compound, the elements are always present in definite proportions by mass.In the given question at first Cu is reacting with O2 to form CuO.

2Cu + O2 → 2CuO

As per the given data, 4.90 g of copper oxide was obtained from 3.92 g of copper. Therefore, the percentage of copper in 4.90g of CuO will be

= (mass of copper / mass of CuO) X 100

= (3.92 / 4.9) X 100

= 80 %

In second experiment, 3.64g of copper is obtained from 4.55g of CuO. So, percentage of copper in this sample of copper oxide will be

= (mass of copper / mass of CuO) X 100

= (3.64 / 4.55) X 100

= 80 %

Thus, we see that percentage of copper in both samples of CuO is the same. This means that copper and oxygen always combine in a fixed ratio by mass to form CuO. So the given data verify the law of constant proportion or definite proportion.


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