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Question

One mole of Chlorine combines with certain weight of a metal giving 111g of its chloride. the same amount of metal can displace 2g of hydrogen from an acid. what is the atomic weight of the metal?

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Solution

let metal be x

Let us assume the metal to be x

Cl2 + x → n* xCl ( n moles)

1 mole of Cl2 contains 71 grams, 71 g of Cl2 gives us 111 g of the metal chloride

We know that it replaces 2g H , i.e. in other words replacing 2 moles of H or 2+ charge

Therefore, our metal has 2+ charge as Ca, Mg etc or 2 moles of metal like Na, K etc.....

as Cl ha 1- charge so its two moles are used in the metal chloride as:

XCl2 type ( for Ca type metals )

2XCl type (for Na type)

so weight of chloride = 111= 2* 35.5 + x

x=40

We know that, Ca and K has this much mass but K has 1 charge so it should use its two moles thus giving us a final weight of 80g

Since, x is 40 g.

Our metal is Calcium with an atomic weight of 40.


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