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Question

Soaps are sodium or potassium salts of long chain carboxylic acids. But soap turns red litmus blue that is they are basic in nature. Why?

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Solution

Saponification:
Ester of higher fatty acids gives potassium or sodium salt of higher fatty acid and glycerol when treated with an alkali.. Sodium or potassium salts of higher fatty acid are known as soaps. This reaction is called saponification (soap making).

fat or oil (ester) + base → glycerol (alcohol) + sodium salt of carboxylic acid(soap)

The presence of strong alkali makes soaps basic. That's why they turn red litmus to blue.

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