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Anomalous Behaviour of Fluorine

Haloalkanes r...

Question

Haloalkanes react with AgCN to form isocynide as cheif product .explain .

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Solution

Haloalkanes react with AgCN to form isocynide as AgCN is mainly covalent and not ionic in nature due to which Ag-C bond do not ionize to from different product.Thus,nitrogen is free to donate electron pair which result in formation isocyanide ( R-NC).

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Q. Haloalkanes react with KCN to form alkyl cyanides as main product while AgCN forms isocyanides as the chief product. Explain.

Q. Assertion :Treatment of chloroethane with a saturated solution of

A g C N

gives ethyl isocyanide as the major product. Reason: Cyanide

(C N^{-})

is an ambident nucleophile.

Q. Which of the following compound will be formed as major product when ethyl chloride reacts with

A g C N

KCN on reacting with haloalkanes form:

Q. Assertion: Ethyl chloride with ethanolic

A g C N

gives ethyl isocyanide as major product.
Reason: In ethyl cyanide, carbon of

C N

s p

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