The correct option is A O2 and He
For adiabatic processes, PVγ=constant
When Pressure decrease, Volume has to increase to maintain the above relation.
Even as Volume increases, the increase is volume would be higher when the exponent γ has a lower value than when the value of γ is higher.
So, when γ is higher, for monoatomic it is 1.6, the value of V is smaller compared to the value of V for which γ is lower, diatomic it is 1.4
Hence, Plot 1 corresponds to lower γ-diatomic-O2
Plot 2 corresponds to higher γ-monoatomic-He