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Question

What is the pH of 1M NaOH, 1M HCl solution, saliva before meal, saliva after meal and lemon juice? Give the pH with complete solutions.

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Solution

pH is defined as the negative log of Hydrogen ion concentration.

pH = -log[H+]

a similar relation is there to express the OH- ion concentration for bases. It is written as

pOH = -log[OH-]

pH and pOH are related by the following expression

pH + pOH = 14

The pH of 1M HCl would therefore be

= - log [H+]

= - log [1] = 0

Therefore pH of 1 M HCl solution is 0. Similarly pOH of 1M HCl will be

= -log[OH-]

= - log [1] = 0

Hence the pH of 1M NaOH will be

= 14 - pOH

= 14 - 0 = 14

The pH of saliva is 6.8. By how much this pH value will change depends upon the kind of meal taken by the person. If a meal is taken which has more acidic content, then pH of saliva will drop. On the other hand, if a meal which has more basic content is taken, the pH will increase. Citric acid is a weak organic acid, hence its pH will be close to 6.


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