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Question

Why are lithium salts commonly hydrated and these of the other alkali ions usually anhydrous?

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Solution

Dear student!
Due to the smallest size of Li+ ion amongst all the alkali metals it can easily attract the water molecule and get that polarized as a result the water molecules get attached to the lithium-cations and the product formed contains water of crystallization.
But the other alkali metal cations have larger size and so they do not get hydrated and form anhydrous compounds.

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