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Question

Why Glass is attacked only by Hydrofluoric acid(HF)?

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Solution

Hydrofluoric acid is a weak inorganic acid but, it is corrosive in nature and also highly penetrating due to small size of F atom.

Hence unlike other acids(HCl, HBr etc) it attacks glass with the formation of fluorosilicate ions [SiF6]2-

The reaction involved can be shown as:

SiO2 + 6HF → [SiF6]2- + 2H+ + 2H2O


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