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Question

Partial reduction of A is selectively done using :


A

Sia2 BH / AcOH

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B

B2H6 / CH3 COOH

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C

B2H6 / AgNO3 - NaOH

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D

Li Al H4

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Solution

The correct option is A

Sia2 BH / AcOH


When using disiamylborane, the bulky disiamyl group facilitates selective partial reduction of the relatively easily accessible double bond outside the cyclohexene ring. Following this, when treated with CH3CH2OH,CH3OH or 91% wet diglyme, the product obtained is:


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