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Question

Pb and Sn are extracted from their chief ore respectively by

A
Self reduction and carbon reduction
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B
Electrolysis and self-reduction
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C
Self reduction and electrolysis
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D
Carbon reduction and self-reduction
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Solution

The correct option is A Self reduction and carbon reduction
PbO and PbSO4 get reduced by PbS itself which is already present in mixture. Since, the reduction took place by mixture itself, hence it is known as self-reduction.
2PbO+PbSΔ3Pb+SO2
PbSO4+PbSΔ2Pb+2SO2
SnO2+CSn+CO2

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