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Standard XII
Chemistry
Chlorides of Phosphorus
PCl5 exists a...
Question
P
C
l
5
exists as solid in the form of
[
P
C
l
4
]
+
[
P
C
l
6
]
−
, and it is a non conductor of electricity.
A
True
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B
False
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C
Ambiguous
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D
None of the above
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Solution
The correct option is
A
True
In solid state, position of ions are fixed, and hence, cannot conduct electricity.
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Similar questions
Q.
P
C
l
5
in solid exists as
P
C
l
+
4
and
P
C
l
−
6
. Also in some solvents its undergoes dissociation
2
P
C
l
5
⇌
P
C
l
+
4
+
P
C
l
−
6
. Find dissociation constant.
Q.
In solid state
P
C
l
5
exists as
Q.
In solid state
P
C
l
5
exist as an ionic solid
[
P
C
l
4
]
+
[
P
C
l
6
]
−
hybridisation state of cation and anion respectively
:
Q.
Phosphorous pentachloride in gaseous phase exists as a monomer. In solid state, it exists as
P
C
l
+
4
ions. The hybrid state of P-atom in
P
C
l
5
is
s
p
3
d
The hybrid states of P - atoms in
P
C
l
+
4
and
P
C
l
−
6
will be:
Q.
Assertion :
P
C
l
5
is a covalent in gaseous and liquid states but ionic in solid state. Reason:
P
C
l
5
in solid state consists of tetrahedral
P
C
l
+
4
cation and octahedral
P
C
l
−
6
anion.
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