PF $_{3}$ can act as a donor molecule while NF $_{3}$ shows little tendency to act as a donor. This is because in PF $_{3}$ , lone-pair on P is easily donated compared to that of N.

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In PF $_{3}$ lone-pair on P is easily donated compared to that of N.

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Ammonia forms a large number of complexes with transition metal ions. Hybridisation easily explains the case of sigma donation capability of $N H_{3}$ and $P H_{3}$ .
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PF3 can act as a donor molecule while NF3 shows little tendency to act as a donor. This is because in PF3, lone-pair on P is easily donated compared to that of N.

In PF3 lone-pair on P is easily donated compared to that of N.

PF $_{3}$ can act as a donor molecule while NF $_{3}$ shows little tendency to act as a donor. This is because in PF $_{3}$ , lone-pair on P is easily donated compared to that of N.

In PF $_{3}$ lone-pair on P is easily donated compared to that of N.