Ph-CH3CrO2Cl2-Aconc- KOH-Rh-CH2OH-B- Product B of given the reaction is-

The correct option is C Ph CO^ _2 CrO_2Cl_2 oxidizes ph CH_3 to ph CHO ph CH_3ph CHO ; Benzaldehyde undergoes Cannizaro reaction to ...

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Chemical Properties of Ethers

Ph-CH3CrO2Cl2...

Question

$P h - C H_{3} C r O_{2} C l_{2} \to (A) c o n c . K O H \to R h - C H_{2} O H + (B)$ . Product (B) of given the reaction is?

P h - C O_{2} H

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P h - C O_{2}^{-}

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P h - C H O

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P h - C H_{3}

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Solution

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C H_{3} C H O + H_{2} N O H - \to C H_{3} C H = N - O H

P h - O H

- C H_{2} - O H

P h - C O_{2} H

- C H_{2} - \oplus N H_{3}

P h - C H = C H - O | | C - C H_{3} \to P h - C H = C H - C O_{2} H

2 P h - C H O - O H ⟶ P h - C H_{2} O H + P H C O_{2}^{\oplus}

P h - C H O O H^{-} - -- \to P h - C H_{2} - O H + P h C O O^{-}

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