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Question

PhCHO+(CH3CO)2O(1) CH3COONa−−−−−−−−−(2) Hydrolysis, ΔAHBrB

The product B is:

A
PhCH=CHCH2Br
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B
PhC|BrHCH2COOH
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C
PhCH2CH(Br)COOH
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D
PhCH=CHCOBr
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Solution

The correct option is B PhC|BrHCH2COOH
PhCHO+(CH3CO)2O(1) CH3COONa−−−−−−−−−(2) Hydrolysis, ΔPhCH=CHCOOH(A)

(A)HBr−−PhC|BrHCH2COOH(B)

Product (A) is getting formed through Perkin reaction. HBr added up to (A) following Markovnikov pathway.

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