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Question

Photon having energy equivalent to the binding energy of 4th state of He+ ion is used to eject an electron from the metal with K.E. 2eV. If electron is further accelerated through the potential difference of 4V then the minimum value of de-Broglie wavelength (in oA) associated with the electron is:
(h=6.6×1034Js,me=9.1×1031kg,1ev=1.6×1019J)

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Solution

Binding energy of 4th state of He+ ion
we know Rydberg's equation here He+ ion z=2
binding energy n2=
given n1=4
1λ=R(z2) (1n21n22)
1λ=R(2)(14212)
1λ=R4
λ=4R
energyofphoton=hcλ
=hc(R4)
=5.43×1019Joules
λ=h2mE=h2mVq
E=2eV
Vq=4ev
λmin=6.626×10342×9.1×1031×4ev
=h1.079×1024=6.1390A

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