Photosynthesis in C4 plants is relatively less limited by atmospheric CO2 because
C4 plants can absorb CO2 even in a much low CO2 concentration while the C3 plants fail to avail it. C4 cycle is much more efficient photosynthetically. Primary Carboxylation of phosphoenolpyruvate acid (PEP) to form oxaloacetic acid (a 4- carbon compound) in presence of enzyme phosphoenolpyruvate carboxylase (PEP carboxylase) is an additional step in the C4 plants that allow an efficient CO2 utilization. Secondary carboxylation to synthesize carbohydrates occurs in bundle sheath.
Hence, the correct answer is 'Primary fixation of CO2 is mediated via PEP carboxylase'.