The correct option is D the primary fixation of CO2 is mediated via PEP carboxylase
C4 plants approximately have 50% higher photosynthesis efficiency than C3 plants as they are relatively less limited by atmospheric CO2.
This is because of the different mechanism of carbon fixation by the two types of photosynthesis.
C3 photosynthesis uses the Calvin cycle for fixing CO2 catalyzed by ribulose-1,5-bisphosphate carboxylase (Rubisco), which takes place inside of the chloroplast in mesophyll cell.
For C4 plants, photosynthetic activities are partitioned between mesophyll and bundle sheath cells that are anatomically and biochemically distinct. The initial carbon fixation is catalyzed by phosphoenolpyruvate carboxylase (PEPC) forming oxaloacetate (OAA) from CO2 and phosphoenolpyruvate (PEP).