Pick out the correct statement with respect to - Mn CN 6-3-A- It is sp 3 d 2 hybridised and octahedralB- It is sp 3 d 2 hybridised and tetrahedralC- It is d 2 sp 3 hybridised and octahedralD- It is dsp 2 hybridised and square planar

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Valence Bond Theory

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Question

Pick out the correct statement with respect to $[M n (C N)_{6}]^{3 -}$

It is $s p^{3} d^{2}$ hybridised and octahedral

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It is $s p^{3} d^{2}$ hybridised and tetrahedral

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It is $d^{2} s p^{3}$ hybridised and octahedral

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It is $d s p^{2}$ hybridised and square planar

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Shape of the molecule having ${d s p}^{2}$ and $d^{2}$ ${s p}^{3}$ hybridisation is respectively:

s p^{3} d^{2}

\begin{matrix} Column - I & Column - II (Complex ion) & (CFSE and hybridisation) a . {[C r (N H_{3})_{6}]}_{3}^{3 +} & (P) 0.0 Δ_{0}, s p^{3} d^{2} - hybridisation b . {[C u (N H_{3})_{6}]}_{3}^{2 +} & (Q) - 0.6 Δ_{0}, s p^{3} d^{2} - hybridisation c . {[F e (H_{2} O)_{6}]}_{2}^{3 +} & (R) - 1.2 Δ_{0}, d^{2} s p^{3} - hybridisation d . {[I r F_{6}]}_{6}^{3 -} & (S) Diamagnetic (T) Paramagnetic \end{matrix}

(i)	$X e F_{2}$	(a)	Central atom is $s p^{3}$ hybridised and has a bent shape.
(ii)	$N_{3}^{-}$	(b)	Central atom is $s p^{3} d^{2}$ hybridised and has an octahedral shape.
(iii)	$P C l_{6}^{-}$	(c)	Central atom is $s p$ hybridised and has a linear shape.
(iv)	$I C l_{2}^{+}$	(d)	Central atom is $s p^{3} d$ hybridised and has a linear shape.

Shape of the molecule having ${d s p}^{2}$ and $d^{2}$ ${s p}^{3}$ hybridisation is respectively:

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