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Question

Pick the correct option based on the data given below.
20 ml (1M) 30 ml (1M) HCl + NaOHNaCl(P)+H2O(1) N=1/5Na2CO3(Q) + HClNaCl(R)+H2O(2) M=2/5NaHCO3(S) + HClNaCl+H2O+CO2(3) N=3/5(4) NA

A
P-2, Q-1, R-3, S-4
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B
P-1, Q-4, R-2, S-1
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C
P-1, Q-1, R-2, S-4
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D
P-2, Q-4, R-3, S-1
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Solution

The correct option is A P-2, Q-1, R-3, S-4
i) HCl+NaOHNaCl(P)+H2O
Here limiting reagent is HCl.
Moles of (P) i.e. NaCl formed=20 ml×1 M=20 mmol
Molarity=mmolTotal vol.=2050=25 M

ii) Na2CO3(Q)+2HCl2NaCl(R)+H2O
Moles of (Q) i.e. Na2CO3 present=20 ml×1 M=20 mmol
Moles of HCl present=30 ml×1 M=30 mmol
Here HCl is limiting reagent.
Moles of (R) i.e. NaCl formed=30 mmol
Molarity=mmolTotal vol.=3050=35 M

Moles of (Q) unreacted=5 mmol
Molarity of Q=550=110 M
Normality of Q=210=15 N

iii) NaHCO3(S) + HClNaCl+H2O+CO2
Molarity of S=1 M

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