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Question

Piston cylinder device initially contains 0.5m3 of nitrogen gas at 400kPa and 27C. An electric heater within the device is turned on and is allowed to pass a current of 2A for 5min from a 120V source. Nitrogen expands at constant pressure and a heat loss of 2800J occurs during the process. R=253kJ/kmolK . The final temperature of nitrogen is

A
2.6C
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B
56.6C
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C
29.6C
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D
5.67C
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Solution

The correct option is D 56.6C
Gas is nitrogen hence diatomicCp=7/2R
Given initial temperature =T0=300K, Initial pressure =P0=400kPa, Initial volume=V0=0.5m3
Applying ideal gas equation, number of moles, n=P0V0/RT=400×0.525/3×300=.08kmol=80mol
Heat supplied =2×5×60×120=72000J=72kJ
Also heat released =2.8 kJ
Net heat absorbed = heat supplied-heat released =nCpΔT=6920080×7/2×25/3×ΔT=69200
ΔT=29.6KT=329.6K
Hence, final temperature is 56.6 degrees.

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