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Question

pKa values of four acids are given below at 25oC. Indicate the strongest acid.

A
2
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B
3
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C
2.5
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D
4
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Solution

The correct option is A 2
Ka represents the ionisation constant of an acid. It is a measure of the strength of the acid, provided the temperature remains constant.
pKa=log(Ka)

When pKa=2
2=log(Ka)
Ka=0.01

When pKa3
3=log(Ka)
Ka=0.001

Similarly, as pKa values increase, Ka value decrease and the acid becomes less strong. Hence smaller the pKa value larger the Ka value and hence stronger the acid.

So, the correct option is A

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