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Standard XII
Biology
Light Reaction
Polar solvent...
Question
Polar solvent favours keto form while non polar solvents favours enol form. Which has the maximum enolic form in CCI4 (1) CH3COCH2COCH3 (2)CH3COCH2COH (3)CH3COCH2COOC2H5 (4)CH3COCH2CH3
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Q.
The conversion of a keto form into enol is enolisation. It depends on structural factor, temperature and nature of solvent. Resonance and hydrogen bonding increases enol content. Enolic form of phenol is more stable than keto form by -13 kcal/mole of energy hence phenol exist exclusively as an enol. Enolic tautomer is less polar due to intramolecular hydrogen bonds than the corresponding keto form.Any polar solvent would decrease the enolisation and favour keto form intramolecular hydrogen bonding stablized enol form by 7kcal/mole and resonance stabilizes enol form by 15 kcal/mole.
Which one of the following compounds has maximum enol content?
Q.
Acetyl acetone in enol form is more stable in polar aprotic solvents due to
Q.
Number of compounds given above where keto form is more dominationg than enol form in benzene solvent, is:
Q.
A polar solvent and high temperature favours to:
Q.
Which of the following has the highest percentage of enol form in Keto-enol equilibrium?
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