Polarization of an anion is distortion of its electron cloud by an adjacently placed cation. Which of the following statement is correct?
A
Minimum polarization is brought about by a cation of low radius.
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B
A large cation is likely to bring about a large degree of polarization.
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C
Maximum polarization is brought about by a cation of high charge.
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D
A small anion is likely to undergo large degree of polarization.
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Solution
The correct option is C Maximum polarization is brought about by a cation of high charge. As per Fajan's Rule: higher the charge, smaller the anion. Greater charge on cation lead to polarization of anion.