Potential difference between centre and surface of the sphere of radius R and uniform volume charge density ρ within it will be :
Using Gauss's law the electric field inside the sphere , E.4πr2=qϵ0=ρ(4/3)πr3ϵ0
or E=ρr3ϵ0
Potential difference between surface and center is V=−∫0RE.dr=−∫0Rρr3ϵ0dr=ρR26ϵ0