Predict R1, A and R2 respectively in the given reaction: CH3−CH2−ClR1−→AR2−→CH3−CH3
A
Alc. KOH, ethene, H2/Pd
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B
Zn, ethene, Na/liq.NH3
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C
Alc. KOH, ethyne, Na/liq.NH3
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D
Zn, ethene, H2/Pd
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Solution
The correct option is A Alc. KOH, ethene, H2/Pd Ist reaction is dehydrohalogenation involves removal of (elimination of) a hydrogen chloride by abstracting β-H from a ethyl chloride in presence of base (alc. KOH) to form ethene.
2nd reaction is hydrogenation of ethene in presence of H2/Pd to give ethane. CH3−CH2−Clalc.KOH−−−−−−→CH2=CH2H2/Pd−−−−→CH3−CH3