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Question

Predict the direction in which G0 for the equilibrium N2(g)+3H2(g)2NH3(g);G0298=33.32 kJ
will change with increase in temperature. Calculate G0 at 500C, assuming the H and S do not change with temperature, that is, H0298=H793 and S0298=S793
H0=92.38 kJ and S0=198.2 J/K
(The eqn. shifts to left with increase in temp., +60.83 kJ).

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Solution

When given in this reaction ΔG is negative and the enthalpy change and entropy change are negative so when we increase the temperature in the reaction the equilibrium shift in the left side

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