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Question

Predict the major product.

A
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B
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C
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D
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Solution

The correct option is C
The reaction proceeds mainly in three steps.
Step 1: Addition of Mg metal (in dry ether) to the given alkyl bromide produces grignard reagent having 2o carbanion.

Step 2: Rearrangement of 2o carbanion through opening of cyclopropane ring to generate 1o carbanion.

Step 3: Abstraction of proton from water molecule.

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